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If a variable is not fixed, (e.g. we do not clamp a piston in a certain position), then because all the accessible states are equally likely in equilibrium, the free variable in equilibrium will be such that Ω {\displaystyle \Omega } is… It can be easily verified that VLJtrunc(rc) = 0, thus eliminating the jump discontinuity at r = rc. Although the value of the (unshifted) Lennard Jones potential at r = rc = 2.5σ is rather small, the effect of the truncation can be… In the presence of an electrostatic field there is Stark splitting which allows molecular electric dipole moments to be determined. Physical Chemistry 3th Castellan - Free ebook download as PDF File (.pdf), Text File (.txt) or read book online for free. Library.pdf - Free download as PDF File (.pdf), Text File (.txt) or read online for free.

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It can be easily verified that VLJtrunc(rc) = 0, thus eliminating the jump discontinuity at r = rc. Although the value of the (unshifted) Lennard Jones potential at r = rc = 2.5σ is rather small, the effect of the truncation can be…

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